Autoionization of Water
Ø
2 water molecules exchange H+
Ø
H
2
O + H
2
O
⇄
H
3
O
+
+OH
-
Ø
K
w
= [H
3
O
+
][OH
-
]= [H
+
][OH
-
]
l
dissociation constant for water
Ø
at 25C, [H
+
]=[OH
-
]=1.0 x 10
-7
Ø
so at 25C, K
w
=1.0x10
-14
Ø
how will change it with temperature?
Ø
Ø
Ø